Nitrosylsulfuric acid

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Nitrosylsulfuric acid
Structural formula of nitrosylsulfuric acid
Ball-and-stick model of the nitrosylsulfuric acid molecule
Names
IUPAC name
Nitrosylsulfuric acid
Other names
nitrosonium bisulfate, chamber crystals
Identifiers
7782-78-7 YesY
ChemSpider 74147 YesY
Jmol 3D model Interactive image
PubChem 82157
  • InChI=1S/HNO5S/c2-1-6-7(3,4)5/h(H,3,4,5) YesY
    Key: VQTGUFBGYOIUFS-UHFFFAOYSA-N YesY
  • InChI=1/HNO5S/c2-1-6-7(3,4)5/h(H,3,4,5)
    Key: VQTGUFBGYOIUFS-UHFFFAOYAM
  • O=NOS(=O)(=O)O
Properties
HNO5S
Molar mass 127.08 g/mol
Appearance pale yellow crystals
Density 1.612 g/mL in
40% sulfuric acid soln
Melting point 73.5 °C (164.3 °F; 346.6 K)
Boiling point decomposes
decomposes
Solubility soluble in H2SO4
Vapor pressure {{{value}}}
Related compounds
Other anions
 NOCl
Other cations
 NaHSO4
Related compounds
 NOBF4
Except where otherwise noted, data are given for materials in their standard state (at 25 °C [77 °F], 100 kPa).
YesY verify (what is YesYN ?)
Infobox references

Nitrosylsulfuric acid is the chemical compound with the formula NOHSO4. It is a colourless solid that is used industrially in the production of caprolactam.[1]

Synthesis and reactions

A typical procedure entails dissolving sodium nitrite in concentrated sulfuric acid in an ice bath:[2][3]

HNO2 + H2SO4 → NOHSO4 +H2O

The molecule can also be viewed as the mixed inorganic anhydride of sulfuric acid and nitrous acid. Alternatively, it can be prepared by the reaction of nitric acid and sulfur dioxide.[4]

NOHSO4 is useful in organic chemistry to prepare diazonium salts from amines. Related NO-delivery reagents include nitrosonium tetrafluoroborate ([NO]BF4) and nitrosyl chloride.

References

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  1. ↑ Lua error in package.lua at line 80: module 'strict' not found.
  2. ↑ Lua error in package.lua at line 80: module 'strict' not found.; Lua error in package.lua at line 80: module 'strict' not found. (diazodization followed by treatment with nitrite)
  3. ↑ Lua error in package.lua at line 80: module 'strict' not found.; Lua error in package.lua at line 80: module 'strict' not found. (diazodization followed by treatment with iodide)
  4. ↑ Lua error in package.lua at line 80: module 'strict' not found. This procedure generates the nitrosylsulfuric acid as an intermediate en route to NOCl.
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